Size - Exclusion Chromatographic NMR of Polymer Mixtures Guillermo

نویسنده

  • Iain J. Day
چکیده

The use of chromatographic stationary phases or solvent modifiers to modulate diffusion properties in NMR experiments is now well established. Their use can be to improve resolution in the diffusion domain or to provide an insight into analyte-modifier interactions and hence the chromatography process. Here we extend previous work using size-exclusion chromatographic (SEC) stationary phases to the investigation of polymer mixtures. We demonstrate that similar diffusion modulation behaviour is observed with an SEC stationary phase which can be understood in terms of size-exclusion behaviour.

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تاریخ انتشار 2014